The theoretical range for a VOR, given a strong-enough signal and ideal conditions (no obstructions or radio/atmospheric interference) is the line-of-sight equation, which is approximately
d = 1.15 * sqrt(h)
where d is the reception distance in nautical miles (use 1.5 instead of 1.15 for statute miles) , and h is your height above the transmitter in feet. So If the VOR is at 2,000 ft MSL and you're flying at 9,000 ft MSL, you're 7,000 ft above the VOR and the furthest you'd reasonably have a faint hope of picking it up in perfect conditions would be
1.15 * sqrt(7,000) =~ 1.15 * 83.67 =~ 96 nm
That's an ideal, though, not necessarily a reality, and not necessarily tested for accuracy by the FAA. In rare cases, the radio beams will bend slightly over the horizon and give you a touch more range.
In my experience, even though DME also follows the line of sight rule, it usually doesn't kick in as early as the VOR signal, and the VOR CDI is pretty wonky at the outside extreme of its range.