500 seems rather high. So #1, Continental, rear cylinder, ‘co-pilot’ side? After takeoff temp comes back to normal? New engine? How new? Hours?
I’d look at what the other CHTs are at, during the same time. If EGT is available, see how they correlate with individual CHTs. Likely no ‘cowl flaps’ to adjust airflow around the engine with this A/C?
Then what about environmental conditions during the high CHT events, OAT? Ground time?
Early in I had some CHT variance with my fwd, right cylinder, lycoming, always low by a good bit. I ended up going with aluminum tape, modest amount. Now my CHTs are often less than 10 degrees of difference.
If you have an honest 500, engine past any ‘break-in’ period, I’d continue to evaluate the issue.