This is the part I still don't follow. In the Seneca IV MM I'm looking at and posted below, the solenoid must be removed to access the poppet valve. Have you removed the solenoid? You dont mention that above. If you did and you still have a different valve then I'd recommend call Piper support which is what I do in situations like this.
But before you call, which valve are you referencing as the deice valve: the control valve or the deflate valve? From your picture it appears the control valve. If so that valve in a normal state is closed and bypasses deice pressure air from the pump overboard. It only opens to allow pressure air into the deice system during a deice cycle of 6 seconds or until 17 psi is reached then it closes again dumping pressure air overboard. So if I understand your post, with electrical power on, when you actuate the wing deice switch on the panel you have verified power at the control valve solenoids but neither control valves open and they continue to remain closed dumping pressure air overboard during the 6 second deice cycle?
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