TKS has STC's for a FIKI installation in several planes, and I recall Barons, Caravans, and C210's. They also do non FIKI retrofits on Bonanzas and others.
Simply adding boots does not provide protection to the props or windshield. Boots require continued maintenance, need replacement, take away around 5k airspeed, and require larger pressure pumps. Then still need a hot plate and heated props or alcohol slinger, which may or may not even be available or STC'd. The boot install alone was around 35k.
For the extra 10k, I went with TKS on my Baron and am happy with the installation. It used the existing prop slingers and spray bar, and has approval for FIKI. Like any anti or deice system, it can be overcome in severe conditions, but I have not encountered this.
The worst conditions I encountered were once over western Michigan and going over Lake Michigan westbound. I had several "outs" available, but the commercial traffic going into Detroit were all calling ice reports, etc. The TKS worked well, and even though the nose and spinners picked up ice, there was no ice on the flying surfaces. Even then it was a little tense, but the system did it's job.
Given the choice, I would pick TKS over boots again any day.