A ball hone would clean it up at this point, and it gives a chance to clean and lap the valves. Go back together with the same rings and your cost is a few bucks in cleaners/compounds, the ball hone, and the labor, add a 1/2" chuck drill if you don't already have one. As long as the valve guides aren't so worn they fail the wobble test, you can just clean it all up and put it back together.
It's really the lead that's the problem, it glues the carbon onto the valve and stem. Getting rid of leaded fuel will lead to considerable economic savings in cylinders in the average plane's life, especially HP engines run hot and rich. That's where you see everyone getting topped at mid time. LOP usually gets cylinders to TBO.