The process is called nucleation. Often, crystals won't form on their own, but will only grow from extant crystals. ice is like this, ice crystals have to be nucleated by something, thus water can become supercooled without freezing.
Steingar is right. You've got supercooled water. Water has some real unique properties, once is that as it freezes it forms crystals (which is why it gets lighter). Given the right conditions, you can prevent the crystals from forming even if the water is below the freezing point.