Couldn't you have some copper cables fabricated?
Sure you could. But it is a change to the type design, which has legal ramifications that might end up costing a bunch more than you counted on if some inspector found out. I don't know about the FAA, but here in Canada any change to the electrical system upstream of the bus is a major modification and therefore needs legal approval.
M22759 wire is not cheap. Copper costs these days, and Tefzel insulation isn't cheap either. This cable runs from the battery contactor up under the floor to the engine compartment and terminates at the starter contactor and is tapped off there to the bus. There is NO fuse or breaker anywhere in that circuit, so you don't want cheap insulation.
Aluminum cable oxidizes inside the crimp terminals. That presents a resistance that slows the starter, but can also generate enough heat to start a fire at one end or the other. I think Bogert has a bit of an article on it.
The Cessna Cardinal had aluminum cables, too. I replaced a set with the STD'd Bogerts. Lots of work under the floor in that tiny space, routing the cable through and getting scratched up good. The aluminum cable had been cut wide open by the bolt on the cowl flap cable attachment. Must have been causing some strange electrical issues at times.
Edit:
Appendix A to Part 43—Major Alterations, Major Repairs, and Preventive Maintenance
(a)
Major alterations—(1)
Airframe major alterations. Alterations of the following parts and alterations of the following types, when not listed in the aircraft specifications issued by the FAA, are airframe major alterations:
(xii) Changes to the basic design of the fuel, oil, cooling, heating, cabin pressurization,
electrical, hydraulic, de-icing, or exhaust systems.